I have got the impression that you need to find someone who is using the Mac, even if they do not use TeXmacs, to help you with the path.
In these days @mgubi and @vdhoeven (both Mac users, and the ones who could have helped you) are not posting, so perhaps you could find somewhere else someone who tells you how to add the necessary path for Maxima (any forum where people answer Mac questions), and after we have that we can get TeXmacs to recognize Maxima I think (I am taking for granted that once you put the Maxima path onto the PATH environment variable, then
(url-exists-in-path? "maxima")
will return #t
and hopefully the rest of the plugin code will work and you will be able to use Maxima.